SUSTAINABLE POLYMER AND COLLOID CHEMICAL ENGINEERING
BE PART OF THE SOLUTION
“Environmental sustainability sits at the heart of our chemical engineering approach to innovate in polymer and colloid science.”
PAPERS
We present the latest of our research findings here on this site. For a complete list of our published works see our publications page.
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Liquid Formulations
SUSTAINABILITY & ENVIRONMENT
From developing greener materials and processes to growing more sustainable supply chains, a new £13.6 million research hub, funded by the Engineering and Physical Sciences Research Council (EPSRC), will help researchers at the University of Warwick tackle some of the UK’s biggest manufacturing challenges.
The new Manufacturing Research Hub in Sustainable Engineering Plastics (SEP) will be led by Professor of Polymer Processes, Ton Peijs, at WMG, and has Professor of Polymer and Colloid Chemical Engineering, Stefan Bon, at the Department of Chemistry as one of the co-investigators.
Phase change materials, or PCMs, can capture, store, and release energy during a phase transition. If we would like to use this concept in a temperature-regulating fluid, we need to disperse the PCMs into a liquid, such as water, that in itself has a high heat capacity and thus the ability to store energy.
Water-based pressure sensitive adhesives (PSAs) are typically made by emulsion polymerization using a low glass transition temperature base monomer, such as n-butyl acrylate or 2-ethyl hexylacrylate, together with a range of functional comonomers. Typically these include a high glass transition temperature comonomer, such as styrene or methyl methacrylate and monomers that can promote wetting and undergo secondary interactions such as (meth)acrylic acid.
Labels are big business. A typical label has multiple layers: a topcoat for protection, the face stock, which contains the message in text and/or images, a pressure-sensitive adhesive, and a release liner, which often has a release coating.
BonLab has designed and developed a concept and prototype for a sustainable solution: a mesh-reinforced pressure-sensitive adhesive for linerless label design.
A fresh lick of paint breathes new life into a tired looking place. Ever wondered how a thin layer of paint is so effective in hiding what lies underneath from vision? Beside colour pigments, and a binder that makes it stick, paints contain microscopic particles that are great at scattering light and turning that thin layer of paint opaque. The golden standard for these opacifiers is small titanium dioxide particles, of dimensions considerably smaller than one micron. Their use is not without controversy, as they pose a significant environmental burden, with a substantial carbon footprint and a questionable impact on human health. Ideally, though, titanium dioxide should be replaced, but the list of safe, high refractive materials is very limited. Here we provide a potential solution.
Ross Jaggers and prof.dr.ir. Stefan Bon at BonLab have now developed technology that allows for temporal and spatial programming of hydrogel objects, which we made from the biopolymer sodium alginate. Key to its design was the combined use of enzyme and metal-chelation know-how.
A Mechanistic Understanding of
POLYMER AND COLLOID SCIENCE
Single-layer graphene is interesting as a flexible 2D material, with xy-dimensions variable up to a centimetre in length and a z-thickness of a single carbon atom. It conducts heat and electricity, has excellent mechanical strength, and is impermeable to gases except hydrogen gas. Its drawback: how to disperse it in a liquid. When you try to do this flexible sheets of graphene tend to stack as a result of attractive van der Waals interactions, making it virtually an impossible material to disperse as single sheets.
Labels are big business. A typical label has multiple layers: a topcoat for protection, the face stock, which contains the message in text and/or images, a pressure-sensitive adhesive, and a release liner, which often has a release coating.
BonLab has designed and developed a concept and prototype for a sustainable solution: a mesh-reinforced pressure-sensitive adhesive for linerless label design.
A mini-emulsion polymerization is a variation on the more conventional emulsion polymerization process in that in the ideal scenario latex particles are formed by monomer droplet nucleation. The monomer droplets are turned into polymer particles.
When we synthesize polymer colloids by emulsion polymerization, molecular surfactants are often employed. These are required to keep the polymer latex particles dispersed in the water phase, so that they do not clump together, a phenomenon known as coagulation. Keeping polymer dispersions stable is especially important in end applications, such as waterborne coatings and adhesives.
Synthetic polymers in most cases do not have one bespoke molecular weight. A sample typically consists of a large number of individual polymer chains, each having a different molecular weight. The average molecular weights and the shape of the molecular weight distribution are a kinetic fingerprint of how to polymer material was made. The resulting molecular weight distribution dictates physical and mechanical properties.
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Emulsion polymerization is of pivotal importance as a route to the fabrication of water-based synthetic polymer colloids. One quest in emulsion polymerization technology that remains challenging and intriguing is control of the particle morphology. It is important because the architecture of the polymer colloid influences its behavioural properties when used in applications. We now report in ACS Nano an elegant innovation in the emulsion polymerization process, which makes use of nanogels as stabilizers and allows us to fabricate Janus and patchy polymer colloids.
Reconfigurable Nanoscale Optical and Mechanical Metamaterials (ReNOMMs)
SUPRACOLLOIDAL METAMATERIALS
Researchers from the University of Cambridge and the University of Warwick have secured £2.3M in UKRI funding to create materials with radically new optical and mechanical properties, that can be produced at scale and low cost.
Labels are big business. A typical label has multiple layers: a topcoat for protection, the face stock, which contains the message in text and/or images, a pressure-sensitive adhesive, and a release liner, which often has a release coating.
BonLab has designed and developed a concept and prototype for a sustainable solution: a mesh-reinforced pressure-sensitive adhesive for linerless label design.
A fresh lick of paint breathes new life into a tired looking place. Ever wondered how a thin layer of paint is so effective in hiding what lies underneath from vision? Beside colour pigments, and a binder that makes it stick, paints contain microscopic particles that are great at scattering light and turning that thin layer of paint opaque. The golden standard for these opacifiers is small titanium dioxide particles, of dimensions considerably smaller than one micron. Their use is not without controversy, as they pose a significant environmental burden, with a substantial carbon footprint and a questionable impact on human health. Ideally, though, titanium dioxide should be replaced, but the list of safe, high refractive materials is very limited. Here we provide a potential solution.
Programmable, Reconfigurable, and Recyclable
DYNAMIC MATERIALS
We set out to develop a prototype for “icy road” warning signs which was able to operate autonomously without the use of electricity, and which could be easily placed onto existing road features, such as street boundary pillars and road safety barriers.
The results from our studies are now published open access in the Journal of Materials Chemistry C from the Royal Society of Chemistry. The conceptual road sign application is a multi-lamellar flexible strip.
In our work published in the Journal of Materials Chemistry B, we present combinations of large, soft hydrogel objects containing different signalling and receiving molecules, can exchange chemical signals. Beads encapsulating one of three species, namely the enzyme urease, the enzyme inhibitor silver (Ag+), or the Ag+ chelator dithiothreitol (DTT), are shown to interact when placed in contact with one another. By exploiting the interplay between the enzyme, its reversible inhibitor, and this inhibitor’s chelator, we demonstrate a series of ‘conversations’ between the beads.
Ross Jaggers and prof.dr.ir. Stefan Bon at BonLab have now developed technology that allows for temporal and spatial programming of hydrogel objects, which we made from the biopolymer sodium alginate. Key to its design was the combined use of enzyme and metal-chelation know-how.